High-quality InAlN near lattice-matched (LM ) to GaN has been grow n on AlN/sapphire tem-plates by metalorganic chemical vapor deposition (M OCVD ) , and characterized by X-ray diffraction (XRD) ,energy dispersive X-ray spectroscopy (EDX ) and scanning electron microscope (SEM ) .Results show that InAlN is lattice matched to GaN indicated by XRD mapping measurements (20-24) ,,and ω-scan-ning rocking curve measurements indicate the high quality of InAlN with the full width at half maximums (FWHMs) of (002) and (102) being as low as 100 and 248 arcsec ,respectively .SEM mappings of InAlN surface show some V-pits distribution .EDX measurements indicate homogeneously special distribution of Al and In .