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MgCl2液滴对1420Al-Li合金腐蚀行为的研究
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Corrosion behavior of 1420Al-Li alloy under MgCl2 solution drops
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    摘要:

    采用开尔文探针对1420Al-Li合金在初始浓度为0.1~1.0 mol/L、体积为4μL的M gCl2液滴下的腐蚀行为进行了研究.结果表明,当M gCl2液滴初始浓度为0.1,0.3 mol/L时,主要发生丝状腐蚀,其电位基线在-0.7~-0.8VSHE范围内,随着合金表面丝状腐蚀生长的停止与开始,出现电位突然增加而后立即下降的现象.当初始浓度增加到1 mol/L时,主要发生孔蚀,随着孔蚀的不断形成与钝化,出现电位突降而后立即回复的现象.当液滴达到环境相对湿度后,随着M gCl2初始浓度的增加阴极极限电流减小,腐蚀速率降低.

    Abstract:

    The corrosion behaviors of 1420Al-Li alloy under 4 μl MgCl2 solution drops with initial concen-tration of 0 .1~1 .0mol/L were studied using a kelvin probe .The results showed that the filiform corro-sion mainly occurred when adding the MgCl2 drops with initial 0 .1mol/L and 0 .3mol/L concentration ,and the Volta potential baseline was at the range of -0 .7 to -0 .8 VSHE .The electric potential increased sud-dently and then decreased immediately ,which could be associated with the filiform corrosion growth stop and initiation .In the case of 1 .0mol/L initial concentration ,the meta-stable pitting corrosion mostly ap-peared ,and the electric potential exhibitted a sudden decrease and then immediate recovery ,which was as-sociated with the initiation and re-passivation of meta-stable pits .After the MgCl2 droplets reached the en-vironmental relative humidity , the cathodic limiting current associated with oxygen reduction was de-creased with increasing the initial MgCl2 concentration and the corrosion rate was decreased .

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李朝兴,徐静,李劲风,邓畅光,陈和兴. MgCl2液滴对1420Al-Li合金腐蚀行为的研究[J].材料研究与应用,2013,(3).

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  • 在线发布日期: 2020-04-26
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