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基于YSZ的电镀Pt复合涂层红外发射率探究
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1.广西大学;2.广东省科学院新材料研究所

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YSZ-based infrared emissivity investigation of electroplated Pt composite coatings
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    摘要:

    随着先进航空发动机推重比的不断提升,涡轮进口温度也在不断攀升,这使得战机的红外辐射强度也大幅提升。对于新一代战斗机而言,红外隐身已经是不得不考虑的问题。为满足高温环境的需要,设计高温部件的涂层材料一般使用耐高温低热导的陶瓷材料作为面层,而现代表面工程技术在目标表面涂覆一层耐高温红外低发射率涂层来降低目标表面发射率实现红外隐身。采用等离子喷涂热障层-电弧离子镀金属层-电镀红外隐身功能层的技术路线可以有效将二者结合起来。本文中样品的制备分别采用了等离子喷涂-物理气相沉积(PS-PVD)技术,与大气等离子喷涂(APS)技术,在DZ40M高温合金基体上制备了不同厚度的7YSZ陶瓷层,然后用电弧离子镀技术制备不同厚度的Al层用以提高表面导电性以便电镀,同时借用Al层的性质使得涂层在真空热处理后整体的结合强度有所提高,最后采用电镀法制备Pt金属层作为红外低发射率层。随后利用场发射-扫描电镜、X射线衍射仪、能谱仪对涂层表面和截面的组织结构及物相进行了分析,并测试了复合涂层的红外发射率与结合强度。研究结果表明,采用Al元素连接电镀Pt层及YSZ热障层,当Al/Pt的厚度比接近1:1时,若采用APS工艺制备YSZ层,复合涂层在真空热处理后红外发射率可以低至0.21,与此同时结合强度仍能达到41MPa,且通过调整Al/Pt层的厚度比,结合强度可以提高至53MPa;若采用PS-PVD工艺制备YSZ层,复合涂层在真空热处理后红外发射率可以低至0.27,且结合强度高达68MPa。

    Abstract:

    As the thrust-to-weight ratio of advanced aero-engines continues to increase, the turbine inlet temperature is also climbing, which makes the intensity of infrared radiation from fighter aircraft also increase dramatically. For the new generation of fighter aircraft, infrared stealth has been a problem that has to be considered. In order to meet the needs of the high temperature environment, the design of high temperature parts of the coating material generally use high temperature low thermal conductivity ceramic materials as the surface layer, and modern surface engineering technology in the target surface coating a layer of high temperature infrared low emissivity coating to reduce the target surface emissivity to achieve infrared stealth. The technical route of plasma spraying thermal barrier layer - arc ion plating metal layer - plating infrared stealth functional layer can effectively combine the two. Using plasma spraying-physical vapour deposition (PS-PVD) technology and atmospheric plasma spraying (APS) technology, a 7YSZ ceramic layer is prepared on the DZ40M high temperature alloy substrate, and then an Al layer is prepared by arc ion plating technology to improve the surface conductivity for plating, and at the same time, the nature of Al is borrowed to make the overall bonding strength of the coating increase, and finally a Pt metal layer is prepared by electroplating. The surface and cross-section of the coatings were analysed by field emission scanning electron microscopy (FESEM), X-ray diffractometer (XRD) and energy spectrometry (ES), and the infrared emissivity and bonding strength of the composite coatings were tested. The results show that the composite coating can still maintain a good bonding strength while keeping a low IR emissivity through the connection of Al metal layers of suitable thickness.

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  • 收稿日期:2024-06-05
  • 最后修改日期:2024-07-03
  • 录用日期:2024-07-05
  • 在线发布日期: 2024-12-13
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