Atomic layer deposition (ALD) is an emerging technology for thin film deposition. The major advantage of ALD is to conformally deposit uniform dense nano films on structures with a high aspect ratio, and therefore, ALD has a wide range of applications in microelectronics, nanotechnology, and so forth. Compared to conventional micrometer-thick films, nanometer-thick ALD films require more accurate characterization methods. Therefore, this paper discusses the characterization methods particularly for the ALD films. In this paper, common characterization methods for the ALD films are discussed mainly from the aspects of film thickness, composition, crystallinity, and morphology properties, and an outlook is also offered on the future directions of the characterization methods.